Quantum dot and well architectures are attractive for infrared optoelectronics, and have led to the realization of compelling light sensors. However, they require well-defined passivated interfaces and rapid charge transport, and this has restricted their efficient implementation to costly vacuum-epitaxially grown semiconductors. Here we report solution-processed, sensitive infrared field-emission photodetectors. Using quantum-dots-in-perovskite, we demonstrate the extraction of photocarriers via field emission, followed by the recirculation of photogenerated carriers. We use in operando ultrafast transient spectroscopy to sense bias-dependent photoemission and recapture in field-emission devices. The resultant photodiodes exploit the superior electronic transport properties of organometal halide perovskites, the quantum-size-tuned absorption of the colloidal quantum dots and their matched interface. These field-emission quantum-dot-in-perovskite photodiodes extend the perovskite response into the short-wavelength infrared and achieve measured specific detectivities that exceed 1012 Jones. The results pave the way towards novel functional photonic devices with applications in photovoltaics and light emission.

译文

:量子点和阱结构对红外光电器件很有吸引力,并导致了引人注目的光传感器的实现。然而,它们需要良好定义的钝化界面和快速的电荷传输,这将它们的有效实施限制在昂贵的真空外延生长的半导体上。在这里,我们报告解决方案处理,敏感的红外场发射光电探测器。我们使用钙钛矿中的量子点,通过场发射演示了光载流子的提取,然后是光生载流子的再循环。我们在操作超快瞬态光谱学中使用以感测偏置相关的光发射和场发射器件中的捕获。所得的光电二极管利用了有机金属卤化物钙钛矿的优异电子传输性能,胶体量子点的量子尺寸调谐吸收及其匹配的界面。这些场发射型钙钛矿中的量子点光电二极管将钙钛矿响应扩展到短波长红外中,并实现了超过1012 Jones的测量比探测率。结果为在光伏和光发射中应用的新型功能性光子器件铺平了道路。

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