In this study, we evaluate the nature of the relationship between particulate matter and total mercury concentrations. For this purpose, we estimate both of the two values in water column over 12-h tidal cycles of the Jade Bay, southern North Sea. Total particulate mercury in 250 mL water samples was determined by oxygen combustion-gold amalgamation. Mercury contents varied from 63 to 259 ng/g suspended particulate matter (SPM) or 3.5-52.8 ng/L in surface waters. Total particulate mercury content (THg(p)) was positively correlated with (SPM), indicating that mercury in tidal waters is mostly associated with (SPM), and that tidal variations of total particulate mercury are mainly due to changes in (SPM) content throughout the tidal cycle. Maximum values for THg(p) were observed during mid-flood and mid-ebb, while the lowest values were determined at low tide and high tide. These data suggest that there are no mercury point sources in the Jade Bay. Moreover, the THg(p) content at low tide and high tide were significantly lower than the values recorded in the bottom sediment of the sampling site (>200 ng/g DW), while THg(p) content during the mid-flood and mid-ebb were comparable to the THg content in the surface bottom sediments. Therefore, changes in THg(p) content in the water column due to tidal forcing may have resulted from re-suspension of underlying surface sediments with relatively high mercury content.

译文

在这项研究中,我们评估了颗粒物与总汞浓度之间关系的性质。为此,我们估计了北海南部玉湾12小时潮汐周期内水柱中的两个值。通过氧燃烧-金汞齐化测定250毫升水样中的总颗粒汞。地表水中的汞含量从63到259 ng/g悬浮颗粒物 (SPM) 或3.5-52.8 ng/L不等。总颗粒汞含量 (THg(p)) 与 (SPM) 呈正相关,说明潮水中的汞主要与 (SPM) 相关,而总颗粒汞的潮汐变化主要是由于整个潮汐周期中 (SPM) 含量的变化。在洪水中期和退潮中期观察到THg(p) 的最大值,而在低潮和涨潮时确定最低值。这些数据表明翡翠湾没有汞点源。此外,低潮和高潮时的THg(p) 含量明显低于采样点底部沉积物中记录的值 (>200 ng/g DW),而中洪和中潮期间的THg(p) 含量与表层底部沉积物中的THg含量相当。因此,由于潮汐强迫,水柱中THg(p) 含量的变化可能是由于汞含量相对较高的下层表层沉积物的重新悬浮所致。

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