In human cataract lenses the UV filters, 3-hydroxykynurenine glucoside (3OHKG) and kynurenine (Kyn) were found to be covalently bound to proteins and the levels in the nucleus were much higher than in the cortex. The levels of the bound UV filters in cataract nuclei were much lower than those in age-matched normal lenses. 3-Hydroxykynurenine could not be detected in cataract lenses. As with normal lenses, protein-bound 3OHKG in cataract lenses was found at the highest levels followed by Kyn. Free UV filter concentrations were also markedly reduced in cataract lenses. This feature may well contribute to the lower protein-bound levels; however, there was no clear relationship between free and bound UV filter contents when individual lenses were examined. We propose that since cysteine is a major site for UV filter binding, the well-documented oxidation of protein sulfhydryl groups during the progression of nuclear cataract may account, in part, for the pronounced decrease in bound UV filters in cataract lenses.

译文

:在人类白内障镜片中,发现紫外线滤光片,3-羟基犬尿氨酸糖苷(3OHKG)和犬尿氨酸(Kyn)与蛋白质共价结合,并且细胞核中的含量远高于皮质。白内障细胞核中结合的紫外线过滤剂的水平远低于年龄匹配的正常晶状体中的水平。在白内障晶状体中未检出3-羟基犬尿氨酸。与正常晶状体一样,白内障晶状体中结合蛋白的3OHKG含量最高,其次是Kyn。白内障晶状体中游离UV过滤剂的浓度也显着降低。此功能很可能有助于降低蛋白结合水平。然而,当检查单个镜片时,游离和结合的紫外线过滤剂含量之间没有明确的关系。我们建议,由于半胱氨酸是紫外线滤光片结合的主要部位,在核性白内障发展过程中,蛋白质硫氢基团的有据可查的氧化可能部分解释了白内障晶状体中结合的紫外线滤光片的明显减少。

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