This study examined metal leaching and retention in pervious concrete with or without embedded particulate matter. Particulate matter was collected from an adjacent parking lot and from a nearby parking garage as examples of weathered and un-weathered particulate matter. Particle size distributions were similar, but metal content was 3-35-fold higher and organic matter content was 3-fold higher in the parking garage particulate matter compared to the parking lot particulate matter. Replicate columns were established with either no particulate added as the control, or 20 g of parking lot or parking garage particulate matter. Synthetic rainwater was passed through the columns at variable rainfall intensity or fixed intensity to assess leaching. Metals were leached at higher concentrations from the parking garage particulate amended column, but from all columns less than 1% of the metal mass leached. Rainfall intensity did not have a large effect on leached metal concentrations, only varying effluent by about 2-fold. Synthetic stormwater with elevated dissolved Cu, Zn, Cd and Pb concentrations was passed through the same columns and metal removal efficiencies were on the order of 85-95%, 30-95%, 60-90%, and 95+% for each metal, respectively. After loading the column with a year's worth of stormwater metal exposure, removal efficiencies in the no particulate and parking lot particulate amended columns decreased, while parking garage particulate amended columns performed similarly with a small drop in Cu and Pb removal efficiencies. Generally, columns with no particulate and parking lot particulate amendments performed similarly, suggesting the pervious concrete is responsible for the majority of the initial metal retention. The parking garage particulate amended columns retained more metals from stormwater, perhaps due to an increase in pH that promoted surface precipitation as hydroxides or carbonate species on the pervious concrete, or due to complexation in the higher concentrations of organic matter and iron oxides in the particulate matter. Overall, metal retention was aided by the presence of organic matter in the particulate matter, but the pervious concrete itself was more important than particulates for metal retention. A strategy to increase metal retention and removal from the environment could involve amending pervious concrete with mixtures of well-defined sorbents to enhance metal retention.

译文

:这项研究检查了有或没有嵌入颗粒物的渗透混凝土中的金属浸出和保留。从风化和未风化的颗粒物的示例中,从相邻的停车场和附近的停车场收集颗粒物。粒度分布相似,但与停车场颗粒物相比,停车场颗粒物的金属含量高3-35倍,有机物含量高3倍。建立重复色谱柱,不添加任何颗粒作为对照,或者不添加20 g停车场或停车库颗粒物质。合成雨水以可变的降雨强度或固定的强度通过色谱柱,以评估浸出。金属从停车场微粒修正柱中以较高的浓度浸出,但从所有柱中浸出的金属量不到金属总量的1%。降雨强度对浸出的金属浓度影响不大,仅使出水变化约2倍。溶解的Cu,Zn,Cd和Pb浓度升高的合成雨水通过相同的色谱柱,每种金属的金属去除率分别为85-95%,30-95%,60-90%和95%,分别。在向色谱柱加载了一年的暴雨金属暴露后,无颗粒物和停车场颗粒物修正柱的去除效率下降,而车库颗粒物修正柱的去除效率相似,铜和铅的去除率略有下降。通常,没有颗粒物和停车场颗粒物改性剂的柱子的性能相似,表明渗透混凝土是造成大部分初始金属滞留的原因。停车场的颗粒物修正柱保留了来自雨水的更多金属,这可能是由于pH的升高促进了透水性混凝土上氢氧化物或碳酸盐种类的表面沉淀,或者是由于颗粒物中较高浓度的有机物和氧化铁络合所致。事情。总体而言,颗粒状物质中有机物的存在有助于金属的保留,但是对于金属保留而言,透水混凝土本身比颗粒更重要。一种增加金属保留和从环境中去除的策略可能涉及用明确定义的吸附剂混合物对透水混凝土进行修正,以提高金属保留率。

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