In this work we used an "in-diffusion" method to study the effects of pH, solution concentration and packing density on Cs diffusion by packing local Taiwan laterite (LTL) into modified capillary columns with 5mm diameter. These packed columns were first pre-equilibrated with synthetic groundwater (GW) for 3 weeks. The diffusion experiments were then carried out at ambient condition for 2 weeks. Our experimental results showed that the Cs diffusion profile fits Fick's second law very well in given experimental conditions, indicating the validity of modified capillary column method. Generally speaking, Cs diffusion in LTL decreases as the pH increases and as Cs concentration decreases. The apparent diffusion coefficient (D(a)) increases from 5.52 x 10(-12) (10(-7)M) to 2.18 x 10(-11) (10(-3)M)m(2)/s, while the effective diffusion coefficient (D(e)) shows slight variation as the Cs concentration changes. Both the derived D(a) and D(e) values decrease as the pH increases, implying that the diffusion mechanisms of Cs nuclide in alkaline and acid environment are different. In addition, our results show that Cs diffusion is unaffected by the given packing density, indicating the interlaminary space is not the major determinant of Cs adsorption and diffusion in LTL.

译文

在这项工作中,我们使用 “扩散内” 方法通过将本地台湾红土 (LTL) 填充到直径5毫米的改性毛细管柱中,研究了pH,溶液浓度和填充密度对Cs扩散的影响。首先将这些填充柱与合成地下水 (GW) 预平衡3周。然后在环境条件下进行扩散实验2周。我们的实验结果表明,在给定的实验条件下,Cs扩散曲线非常符合Fick第二定律,表明改进的毛细管柱方法的有效性。一般来说,随着ph值的增加和Cs浓度的降低,LTL中的Cs扩散减小。表观扩散系数 (D(a)) 从5.52 × 10(-12) (10(-7)M) 增加到2.18 × 10(-11) (10(-3)M)m(2)/s,而有效扩散系数 (D(e)) 随着Cs浓度的变化而略有变化。随着ph值的增加,衍生的D(a) 和D(e) 值均降低,这表明Cs核素在碱性和酸性环境中的扩散机理不同。此外,我们的结果表明,Cs扩散不受给定堆积密度的影响,这表明层间空间不是LTL中Cs吸附和扩散的主要决定因素。

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