An assessment of potential methods suitable for degradation and/or reduction of refractory organics was performed on landfill leachate from SYSAV AB, Malmö, Sweden. Pretreatment of the leachate was performed in a sequence batch reactor designed for nitrification in activated sludge. Oxidation of the leachate was then O3, O3/pH adjustment (pH 9 and 10), H2O2, O3/H2O2 and performic acid in lab-scale reactors. The degradation of organic material was followed with chemical oxygen demand (COD) measurements for all experiments except for the performic acid treatment for which total organic carbon (TOC) measurements were used. The potential degradation of refractory organics into biodegradable organic material was analysed by subsequent oxygen uptake rate (OUR) measurements in laboratory batch reactors. Ozonation of biologically pre-treated leachate increased reduction of the organic material. The most biodegradable organic material was produced after oxidation with only ozone and ozonation at pH 9. Performic acid did not reduce the content of organic material in the leachate. However, a combination of biological pretreatment, chemical oxidation with O3/H2O2 and a subsequent biological process resulted in the most efficient oxidation method for the tested leachate.

译文

对瑞典马尔默SYSAV AB的垃圾填埋场渗滤液进行了适合降解和/或减少难降解有机物的潜在方法的评估。渗滤液的预处理是在设计用于活性污泥硝化的顺序分批反应器中进行的。然后在实验室规模的反应器中,渗滤液的氧化是O3,O3/pH调节 (pH 9和10),H2O2,O3/H2O2和过甲酸。除使用总有机碳 (TOC) 测量的过甲酸处理外,所有实验均对有机材料的降解进行化学需氧量 (COD) 测量。通过随后在实验室间歇反应器中进行的氧气吸收率 (OUR) 测量,分析了难熔有机物可能降解为可生物降解的有机材料。生物预处理渗滤液的臭氧化增加了有机材料的减少。最可生物降解的有机材料是在仅用臭氧和臭氧化在pH 9下氧化后产生的。过甲酸不会降低渗滤液中有机物质的含量。然而,生物预处理,O3/H2O2的化学氧化以及随后的生物过程相结合,可以为测试的渗滤液提供最有效的氧化方法。

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