In a nanoplasmonic context, copper (Cu) is a potential and interesting surrogate to less accessible metals such as gold, silver or platinum. We demonstrate optical trapping of individual Cu nanoparticles with diameters between 25 and 70 nm and of two ionic Cu nanoparticle species, CuFe2O4 and CuZnFe2O4, with diameters of 90 nm using a near infrared laser and quantify their interaction with the electromagnetic field experimentally and theoretically. We find that, despite the similarity in size, the trapping stiffness and polarizability of the ferrites are significantly lower than those of Cu nanoparticles, thus inferring a different light-particle interaction. One challenge with using Cu nanoparticles in practice is that upon exposure to the normal atmosphere, Cu is spontaneously passivated by an oxide layer, thus altering its physicochemical properties. We theoretically investigate how the presence of an oxide layer influences the optical properties of Cu nanoparticles. Comparisons to experimental observations infer that oxidation of CuNPs is minimal during optical trapping. By finite element modelling we map out the expected temperature increase of the plasmonic Cu nanoparticles during optical trapping and retrieve temperature increases high enough to change the catalytic properties of the particles.

译文

:在纳米等离子体的背景下,铜(Cu)是潜在的有趣替代物,是诸如金,银或铂之类难于接触的金属的替代品。我们演示了使用近红外激光对直径在25至70 nm之间的单个Cu纳米颗粒以及两种离子型Cu纳米颗粒CuFe2O4和CuZnFe2O4进行光阱捕获的过程,直径分别为90 nm,并在实验和理论上量化了它们与电磁场的相互作用。我们发现,尽管尺寸相似,但铁氧体的俘获刚度和极化率显着低于Cu纳米粒子,因此推断出不同的光粒子相互作用。在实践中使用铜纳米粒子的一个挑战是,暴露于正常大气后,铜会被氧化层自然钝化,从而改变其物理化学性质。我们从理论上研究了氧化物层的存在如何影响Cu纳米粒子的光学性能。与实验观察结果的比较表明,在光阱过程中,CuNPs的氧化作用极小。通过有限元建模,我们可以绘制出在光捕获过程中等离激元Cu纳米粒子的预期温度升高情况,并且检索到的温度升高幅度足以改变颗粒的催化性能。

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