Proper assessment of soil cadmium (Cd) concentrations is essential to establish legislative limits. The present study aimed to assess background Cd concentrations in soils from the state of São Paulo, Brazil, and to correlate such concentrations with several soil attributes. The topsoil samples (n = 191) were assessed for total Cd contents and for other metals using the USEPA 3051A method. The background concentration was determined according to the third quartile (75th). Principal component analysis, Spearman correlation, and multiple regressions between Cd contents and other soil attributes (pH, cation exchange capacity (CEC), clay content, sum of bases, organic matter, and total Fe, Al, Zn, and Pb levels) were performed. The mean Cd concentration of all 191 samples was 0.4 mg kg(-1), and the background concentration was 0.5 mg kg(-1). After the samples were grouped by parent material (rock origin) and soil type, the background Cd content varied, i.e., soils from igneous, metamorphic, and sedimentary rocks harbored 1.5, 0.4, and 0.2 mg kg(-1) of Cd, respectively. The background Cd content in Oxisols (0.8 mg kg(-1)) was higher than in Ultisols (0.3 mg kg(-1)). Multiple regression demonstrated that Fe was primarily attributed to the natural Cd contents in the soils (R (2) = 0.79). Instead of a single Cd background concentration value representing all São Paulo soils, we propose that the concentrations should be specific for at least Oxisols and Ultisols, which are the primary soil types.

译文

正确评估土壤镉 (Cd) 浓度对于建立立法限制至关重要。本研究旨在评估巴西圣保罗州土壤中的背景Cd浓度,并将这些浓度与几种土壤属性相关联。使用USEPA 3051A方法评估表土样品 (n   =   191) 的总Cd含量和其他金属含量。根据第三个四分位数 (第75个) 确定背景浓度。进行了主成分分析,Spearman相关性以及Cd含量与其他土壤属性 (pH,阳离子交换能力 (CEC),粘土含量,碱,有机质和总Fe,Al,Zn和Pb含量) 之间的多元回归。所有191样品的平均Cd浓度为0.4 mg kg(-1),背景浓度为0.5 mg kg(-1)。根据母体材料 (岩石来源) 和土壤类型对样品进行分组后,背景Cd含量变化,即来自火成岩,变质岩和沉积岩的土壤分别藏有1.5,0.4和0.2 mg kg(-1) 的Cd,分别。背景Cd在Oxisols (0.8 mg kg(-1)) 中的含量高于在Ultisols (0.3 mg kg(-1)) 中的含量。多元回归表明,Fe主要归因于土壤中的天然Cd含量 (R (2)  =   0.79)。代替代表所有圣保罗土壤的单个Cd本底浓度值,我们建议该浓度应至少针对主要土壤类型的oxisol和ultisol特定。

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